Overview of GTL

GTL or Gas to Liquids technology is the chemical process by which natural gas is converted to liquid products such as diesel or methanol. Dason Technology is an early stage Company that owns a shallow bed high throughput syngas (SBHTX) technology. The patented technology is a game changer for the Natural Gas to Syngas stage of the GTL process.

Process flow diagram and schematic for compact 200 barrel/day GTL plants

GTL Process

The reactions occur in phases, and the key to all GTL processes is the intermediary product Syngas. Syngas has the chemical composition to be easily refined into a variety of useful liquid products. Traditionally the bulk of capital investment for GTL plants has been for the first part of the reaction which produces Syngas. Dason's goal is to significantly improve this step by increasing efficiency and decreasing plant size and costs.

Why GTL?

An Alternative and Supplement to Crude Oil

The world demand for oil is growing at a rapid pace, while the world supply of oil is limited. As more oil is extracted production costs rise due to the rapid usage of land based and shallow water oil supplies and increasing substitution for more expensive sources such as oil sands, heavy oil, and deep water oil. The price of oil is not only sensitive to market economics, but also to geopolitical factors. The world supply of natural gas on the other hand is largely untapped, and could be used to supplement and extend the supply of crude oil. Recent discoveries of immense natural gas deposits, and technological innovations allowing for the extraction of shale gas likely will keep the price of gas low for the foreseeable future.

Developing Untapped Markets

Currently natural gas reserves must be near a pipeline, or facilities where it can be compressed or converted into LNG (liquefied natural gas) in order to be transported. Such infrastructures are capital intensive and only economically feasible for large gas deposits, and are unsuitable for gas located in remote areas or deepwater platforms. When drilling for oil under these conditions, natural gas pockets that are uncovered are frequently flared, or burned. This is not only a waste of a precious resource, but is a source of pollution and fines. As of 2007, the World Bank estimated that $30 billion worth of gas is still being flared annually. In addition there exists an estimated 3000 TCF (proven + probable + possible), as much as 40% of the world's gas supply, considered "stranded" and left undeveloped.

Profitability

GTL technology directly impacts a company's bottom line, by allowing it to convert unused gas assets into cash flow and revenue. The economics of gas and crude oil prices also make GTL operations extremely profitable and desirable.

Clean Fuel Focus

Fuels produced from GTL are significantly cleaner than those refined from conventional crude oil. GTL fuels contain only a fraction of the pollutants of conventional diesel, and can be mixed with refined crude products to create clean fuels that meet rising governmental emissions standards. In addition the potential to reduce green house gas emissions and air pollution from flaring has made GTL one of the most sought after technologies.

Licensing/joint venture business model with oil and gas producers

  • In addition to flare gas projects, there are sizeable markets for ammonia and methanol where our technology could also make a huge impact
  • 140 million tons of ammonia was produced globally in 2013. If the SCOR technology is used, the natural gas consumption can be reduced by 15%, which equals 682 million MMBtu or $2.1 billion at a $3/MMBtu price.
  • 61 million tons of methanol was produced globally in 2013. Expected production will reach 109 million tons in 2023. If the SBHTX technology is used, the natural gas consumption can be reduced by 20%.
  • More than 40% of gas reserve in the world is "stranded". The technology can be used to produce oil at these fields profitably






    • GTL expertise
    • New, exciting technology
    Design/Engineering Services Technology

    Natural Gas

    Capital

    Licensing fees

    Producers that have flare or stranded gas properties, and can get added value to operations from Dason

    Lack GTL technology licenses or internal patents

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The Existing GTL Market

The most common industrial method is currently steam methane reforming. Major integrated oil companies have large GTL projects using this technology. Steam methane reforming is an extremely mature technology, but only very minor improvements have been made since its discovery and key inefficiencies are still prevalent. Steam methane reforming produces a product that is chemically not optimal for diesel production.The reactors are very large and capital intensive, and thus only suitable on a very large scale. In addition the reaction can only occur in a very high temperature range, requiring the burning of valuable natural gas to fuel the reaction producing higher carbon emissions and causing wear on equipment and catalysts.

The demand for smaller scale reactors that are more efficient and portable has led major integrated oil companies and technology firms to invest hundreds of millions of dollars for research into other designs. The most promising process is Partial Oxidation, but it is currently not commercially viable due to low catalyst lifespan.

Dason's patented technology is a commercially viable form of Catalytic Partial Oxidation, we believe it will revolutionize the market for GTL by meeting key industry needs for efficiency and size. (To learn more about our Technology click here)

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Dason Process

Dason's reactor combines natural gas with purified O2 and a catalyst. The resulting reaction has an extremely high conversion rate and requires no heat. The Syngas produced is chemically ideal for diesel production. Further Dason's reactor design allows it to be applicable to both small scale and large scale operations without losing efficiency.

Dason Technology vs Competitors

Dason's technology is superior to existing processes. In addition, it is highly appealing to major oil and gas firms because of its modular nature. It can replace the syngas production phase of existing plants, allowing for parallel construction and minimal plant shutdown time.

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Pilot Plant

Dason constructed a pilot plant in Chonqing, China in conjunction with the Chongqing Research Institute of Chemical Industry (www.ccqci.com). Upon completing the pilot plant test runs CCQCI and Dason applied for a research grant and were awarded the maximum amount of 5 million RMB from the China National Development and Reform Committee for support to build a commercial demonstration plant with the Chongqing He Feng Chemical Plant for its pursuit of a technology that holds the future to supplying growing energy needs in an environmentally conscious way.

Pilot Plant Heater

Pilot Plant Test Results

Superior performances of Dason's SCTR syngas technology demonstrated by one-year pilot tests

Dason's technology increased efficiency and quality of the products, while reducing CO2 production.

Superior performances of PNNL's MTMX reactor demonstrated by single-tube tests

  • >95% one-pass CO2 conversion with CH4 selectivity <10% is achievable at H2/CO=2/1
  • The same catalyst has a few times higher activity in the monolith form than in the crushed particle form under the same conditions

Results from Liu et al. AIChE J. 58(2012) 2820-2829

1/2" OD stainless steel reactor tube with monolith catalyst insert

Comparison of the same catalyst in different forms

Case Study: Our technology applied to offshore GTL

Steam reforming reactor has large footprint and low carbon efficiency for GTL

  • Malaysia government will start to fine for flaring gas starting in 2017.
  • We were invited to present our technology to Petronas in 2013.
  • Malaysia Scomi Group built a lab syngas reactor at the Universiti Sains and tested our patented catalyst in 2015.
  • Scomi and Petronas are discussing plans to to build a 200 bpd demonstration GTL plant for offshore in 2018.
  • 200 bpd is economically suitable for the first plant. It takes less than 4 years to reach breakeven at the oil price of $60/bbl and operation cost of $25/bbl. PNNL FT reactor can produce 50% wax, which the price is stable at $200/bbl.
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